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Match the enthalpy of formation with the appropriate Group 17 hydrogen halide --92.3 kJ mol-1


A) HI
B) HCl
C) HF
D) HBr

E) A) and D)
F) C) and D)

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As Group 14 is descended, the hydrides become less stable.

A) True
B) False

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The Periodic Table of the elements forms four different types of hydride. Match the type of hydride with the appropriate compound. -KH


A) Electron-rich hydride
B) Electron-deficient hydride
C) Ionic hydride
D) Electron-precise hydride

E) A) and D)
F) B) and D)

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Match the enthalpy of formation with the appropriate Group 17 hydrogen halide --271.1 kJ mol-1


A) HI
B) HCl
C) HF
D) HBr

E) None of the above
F) A) and D)

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BH4- is using in organic chemistry as a _______ agent where it is a source of H- ions

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The C-H bond of an alkane has an IR absorption for C-H at 2930 cm-1, the analogous C-D absorption would be observed at 2344 cm-1.

A) True
B) False

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The Periodic Table of the elements forms four different types of hydride. Match the type of hydride with the appropriate compound. -AsH3


A) Electron-rich hydride
B) Electron-deficient hydride
C) Ionic hydride
D) Electron-precise hydride

E) B) and C)
F) A) and B)

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Which of the following points suggests that the first hydride in Groups 14-17 exhibit hydrogen bonding. Please select all that apply.


A) There is a steady increase in the boiling point of the hydrides from the second row onwards but the boiling point of the hydride for the first element in any group is anomalously high.
B) There is a steady increase in the melting point of the hydrides from the second row onwards but the boiling point of the hydride for the first element in any group is anomalously high.
C) There is a steady decrease in the boiling point of the hydrides from the second row onwards but the boiling point of the hydride for the first element in any group is anomalously high.
D) There is a steady decrease in the melting point of the hydrides from the second row onwards but the boiling point of the hydride for the first element in any group is anomalously high.

E) All of the above
F) None of the above

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Liquid ammonia can undergo self-ionisation to form NH2- and NH4+ .

A) True
B) False

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Cerium hydride has a structure based on the fluorite structure where cooperative reorganisation of the anion sublattice allows extra hydrogen to be incorporated inside the structure such that x = 0.25. On strong heating all the hydrogen can be liberated from the structure. What percentage of its own mass in hydrogen can Ce absorb within the structure when x =0.25. RAM (g mol-1) of Ce = 140.12, H = 1.01.


A) 1.58%
B) 1.62%
C) 2.18%
D) 2.21%

E) C) and D)
F) B) and C)

Correct Answer

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